Strain-rate frequency superposition: a rheological probe of structural relaxation in soft materials.
نویسندگان
چکیده
The rheological properties of soft materials often exhibit surprisingly universal linear and nonlinear features. Here we show that these properties can be unified by considering the effect of the strain-rate amplitude on the structural relaxation of the material. We present a new form of oscillatory rheology, strain-rate frequency superposition (SRFS), where the strain-rate amplitude is fixed as the frequency is varied. We show that SRFS can isolate the response due to structural relaxation, even when it occurs at frequencies too low to be accessible with standard techniques.
منابع مشابه
Prediction of long and short time rheological behavior in soft glassy materials.
We present an effective time approach to predict long and short time rheological behavior of soft glassy materials from experiments carried out over practical time scales. Effective time approach takes advantage of relaxation time dependence on aging time that allows time-aging time superposition even when aging occurs over the experimental time scales. Interestingly, experiments on a variety o...
متن کاملProbing linear and nonlinear microrheology of viscoelastic fluids
Bulk rheological properties of viscoelastic fluids have been extensively studied in macroscopic shearing geometries. However, little is known when an active microscopic probe is used to locally perturb them far from the linear-response regime. Using a colloidal particle dragged periodically by scanning optical tweezers through a viscoelastic fluid, we investigate both, its linear and nonlinear ...
متن کاملMicrophase Separation and Rheological Properties of Polyurethane Melts. 1. Effect of Block Length
A series of polyesterurethanes with differing block length and constant composition have been synthesized for rheological studies. Hard segments based on isophorone diisocyanate and 1,4butanediol and soft segments based on polycaprolactone to ensure high thermal stability and to prevent high melting point crystallinity enabled long-duration rheological characterization at high temperatures. DSC...
متن کاملAgeing and Rheology in Soft Materials
We study theoretically the role of ageing in the rheology of soft materials. We define several generalized rheological response functions suited to ageing samples (in which time translation invariance is lost). These are then used to study ageing effects within a simple scalar model (the “soft glassy rheology” or SGR model) whose constitutive equations relate shear stress to shear strain among ...
متن کاملGlass transition and rheological redundancy in F-actin solutions.
The unique mechanical performance of animal cells and tissues is attributed mostly to their internal biopolymer meshworks. Its perplexing universality and robustness against structural modifications by drugs and mutations is an enigma in cell biology and provides formidable challenges to materials science. Recent investigations could pinpoint highly universal patterns in the soft glassy rheolog...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Physical review letters
دوره 98 23 شماره
صفحات -
تاریخ انتشار 2007